Due to their large size, and early transition metals tend to have high coordination numbers.Different ligand structural arrangements result from the coordination number. for two-coordination. Coordination compound pdf. Due to the use of ligands of different types (which results in irregular bond lengths; the coordination atoms do not follow a points-on-a-sphere pattern), due to the size of ligands, or due to (see, e.g., ):. Most structures follow the points-on-a-sphere pattern (or, as if the central atom were in the middle of a where the corners of that shape are the locations of the ligands), where orbital overlap (between ligand and metal orbitals) and ligand-ligand repulsions tend to lead to certain regular geometries. The most observed geometries are listed below, but there are many cases that deviate from a regular geometry, e.g.
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